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WHAT'S REALLY
IN A CAN OF PAINT?
Paint
is a creation of man used from the beginning of recorded history
-- from the caves of Lascaux in
France
to the ceiling of the Sistine Chapel, on the figureheads of the
Spanish ships which founded the
New World
, to the decorative symbols on teepees of Native Americans. It
is used for decoration, for communication, as a preservative and
as a maintenance tool. Today, paint has evolved into the
protector, preserver and beautifier of home, workplace, public
spaces and even houses of worship.
A thin film of paint -- a few
thousandths of an inch thick -- protects, seals, hides, and
decorates. Simply put, paint offers long term protection at a
very moderate price. It keeps existing structures from
deteriorating and, in so doing, preserves natural resources such
as trees, water, and a variety of energy sources. To further
appreciate the merits of paint, it is important to understand
what actually goes into the can.
Paint is a simple mixture of
ingredients including pigments, a binder and a diluent, or
thinner (in latex paint is it water; in solvent paints, it is a
petroleum solvent).
Today's pigments, not unlike the
mud, blood and chalk used centuries ago, provide the texture,
color and hiding properties of paint. The pigments, usually in
the form of dry powder, can be organic (containing carbon),
inorganic (no carbon), synthetic or naturally-occurring. Today,
with the utmost concern for consumer safety, architectural
coatings are formulated to be as safe as possible by carefully
selecting pigments. No longer in uses in consumer paints are
pigments which were found to pose potential health hazards
because they contained chromates, lead, soluble barium, or
asbestos.
Titanium dioxide is the primary
pigment ingredient that provides hiding in light color paints.
While any powder, even baby powder, can pose a health hazard if
inhaled in high concentrations, titanium dioxide which is also
used in cosmetics, soaps and certain food products, when used in
a paint film is not respirable and poses no risk to the user.
Other inert pigments include calcium carbonate (limestone),
talc, clay, sand (silica). All of these are naturally occurring
materials that are tightly bound in the paint film and
contribute various properties like gloss control, flow, and film
build. Iron oxides are inorganic color pigments, chemically akin
to rust on metal, that are used to produce reds and yellows.
The binder portion of architectural
coatings consist of synthetic and natural resins which start out
as liquids but dry to form tough durable films. The properties
of the binder largely determine the properties of the paint
film. In waterborne coatings the binder is usually a latex
emulsion composed of vinyl and/or acrylic copolymers. In
solventborne coatings the binder is usually an alkyd, which is a
natural drying oil modified chemically to be especially tough
and long-lasting.
As most people know, today's latex
emulsion paints are thinned with water and represent the
ultimate in safety and ease of use. Solvent-based or oil paints
are thinned with petroleum solvent which make them less
convenient and require more care to be used safely. Over the
years, use of solventborne paint has diminished because of
concern over volatile organic compounds (VOCs). However,
solventborne paints still play an important role today because
of their unique durability and adhesion properties.
Before using any coating carefully
read and follow label instructions.
Other ingredients in paint, called
"additives," impart a variety of properties including
flow, stability, drying, defoaming, mildew resistance and
viscosity.
ADDITIVES
Some additives caused health
concerns in the past and have been removed or greatly reduced in
modern coatings.
Formaldehyde
is no longer added to paints or resins. At one time, it served
as a biocide to prevent bacterial degradation of the paint. It
was replaced over the last decade with ingredients commonly used
in household products and cosmetics.
Mercury
which was added to coatings
as a biocide after World War II (when it was also used in
medicines) was eliminated from all paints by Benjamin Moore in
1970. By 1991 mercury in paint was regulated by EPA and was
removed by all manufacturers.
Lead
was eliminated from consumer products by Benjamin Moore more
than 20 years ago and by the industry at large over ten years
ago. Lead was used in many forms over the years and provided
hiding, color, drying, and corrosion resistance in architectural
and industrial maintenance coatings. By the 1970's lead use was
limited to drying, corrosion resistance and some industrial
maintenance colors.
Other additives:
Coalescents
(a.k.a. film forming aids) are solvents used in waterborne
coatings which help fuse, or coalesce, latex particles in latex
emulsion paints during the drying process. They make possible
better paint films by permitting the use of harder resins in the
coatings formulation. These harder resins result in interior
paints that are scrub resistant and durable.
Anti-skinning agents,
used only in solventborne coatings, prevent undesirable surface
drying, or skinning, in the container during storage and
shipment.
Pigment suspending aids,
dispersants, and surfactants
are present in most paints in very small quantities. They impart
stability and promote shelf-life.
Viscosity and flow enhancers,
provide superior application properties, as their description
implies. They are needed to achieve the best possible hiding and
film appearance.
While solventborne coatings use is
on the decline, especially in the consumer sector, these paints
still provide important, unique properties not always available
in waterborne coatings. Properties at which solventborne
coatings excel include:
Rust-inhibitive and other special
primers, such as stainblockers.
Stains, such as wood stain for
furniture refinishing and exterior semi-transparent finishes.
Varnishes, such as clear finishes
for interior use and exterior varnishes, such as marine.
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